Product ID:GLV (OLD FORMULA)
MSDS Date:09/01/1985
FSC:6850
NIIN:00N010503
MSDS Number: BHNSX

STATE CHEMICAL MANUFACTURING COMPANY

3100 HAMILTON AVENUE
CLEVELAND, OH 44114

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: <20%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <20%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <20%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPANE

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: <15%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT; 9192

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HARMFUL OR FATAL IF SWALLOWED OR
DELIBERATELY INHALED.
Explanation of Carcinogenicity:METHYLENE CHLORIDE:INADEQ EVID FOR
CARCIN IN HUM/SUFF IN ANIM (IARC 1987).ACGIH A2=SUSPECTED HUM
CARCIN (1988-1989).
Effects of Overexposure:EYES:DIRECT CONTACT CAN CAUSE
IRRITATION.SKIN:DIRECT CONTACT CAN CAUSE
IRRITATION.INGEST:DANGER.HARMFUL OR FATAL IF SWALLOWED.INHAL:VAPOR
HARMFUL.DELIBERATE INHALATION OF THE CONTENTS CAN BE HARMFUL O R
FATAL.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:FLUSH EYES IMMEDIATELY WITH PLENTY OF COOL WATER FOR AT
LEAST 15 MINUTES.CONTACT PHYSICIAN.DO NOT WEAR CONTACT LENSES WHEN
WORKING WITH THIS PRODUCT.SKIN:WASH THOROUGHLY WITH SOAP AND
WATER.IF IR RITATION PERSISTS,CONTACT A PHYSICIAN.INGEST:DO NOT
INDUCE VOMITING.CALL A PHYSICIAN IMMEDIATELY.CONTAINS TOLUENE AND
XYLENE.INHAL:REMOVE PERSON TO FRESH AIR.IF IRRITATION
PERSISTS,CONTACT PHYSICIAN.

Flash Point Method:TOC
Flash Point:SEE SUPP DATA
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA AND FULL PROTECTIVE
GEAR .KEEP CANS COOL.SHIELD PERSONNEL FROM BURSTING,VENTING OR
RUPTURING CONTR.DO NOT SPRAY NEAR OPEN FLAME.
Unusual Fire/Explosion Hazard:EXPOSURE TO TEMPERATURE ABOVE 120F,48.89C
MAY CAUSE CANS TO VENT,RUPTURE OR BURST.HAZARDOUS PRODUCTS:CARBON
DIOXIDE,CARBON MONOXIDE,HYDROGEN CHLORIDE,PHOSGENE.

Spill Release Procedures:REMOVE ALL SOURCES OF HEAT,SPARKS OR OPEN
FLAME.VENTILATE THE AREA OF SPILL.ABSORB EXCESS ON STATE OIL
ABSORBANT,SAND OR VERMICULITE.WASH RESIDUE WITH SOAP AND WATER.
Neutralizing Agent:N/K

Handling and Storage Precautions:DO NOT PUNCTURE OR INCINERATE
CANS.EXTREMELY FLAMMABLE.DO NOT USE OR STORE NEAR SPARKS OR OPEN
FLAME.VAPORS HARMFUL OR FATAL IF DELIBERATELY INHALED.
Other Precautions:DO NOT STORE IN STRONG SUNLIGHT OR WHERE TEMPERATURES
MAY EXCEED 120F,48.89C.CONTENTS UNDER PRESSURE.READ & FOLLOW ALL
LABEL DIRECTIONS/PRECAUTIONS BEFORE USE.FOR
INDUSTRIAL/INSTITUTIONAL USE ONLY.KEE P OUT OF THE REACH OF (SEE
SUPP)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .AVOID BREATHING CONCENTRATED SPRAY MIST OR
VAPORS OF STATE GLV.
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:RECOMMENDED.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:N/K
Work Hygienic Practices:N/K
Supplemental Safety and Health
FL PT:<20C,-6.64C.POSITIVE FLAME EXTENSION.% VOLAT BY WT:60.OTHER
PREC:CHILDREN.NO SMOKING IN AREA OF USE.DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING,OPEN FLAMES OR HOT SURFACES.HEAT AND/OR UV
R ADIATION MAY CAUSE THE FORMATION OF HCLAND/OR PHOSGENE .DO NOT
WEAR CONTACT LENSES WHILE USING THIS PRODUCT.

Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:N/K
Evaporation Rate & Reference:N/K
Solubility in Water:NEGLIGIBLE
Appearance and Odor:A GRAY MATTE AEROSOL SPRAY WITH A SOLVENT ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS AND STRONG CAUSTICS.MAY AFFECT SOME PLASTICS.
Stability Condition to Avoid:EXPOSURE TO TEMPERATURE ABOVE
120F,48.89C,SPARKS AND OPEN FLAME.
Hazardous Decomposition Products:BURNING GLV MAY RESULT IN THE
FORMATION OF CARBON DIOXIDE,CARBON MONOXIDE,HYDROGEN CHLORIDE OR
PHOSGENE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .DO NOT PUNCTURE OR INCINERATE
CANS.GIVE CANS TO A DISPOSAL SERVICE EQUIPPED TO SAFELY DISPOSE OF
PRESSURIZED CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.